Intercalation and Push-Out Process with Spinel-to-Rocksalt Transition on Mg Insertion into Spinel Oxides in Magnesium Batteries

Intercalation and Push‐Out Process with Spinel‐to‐Rocksalt Transition on Mg Insertion into Spinel Oxides in Magnesium Batteries

On the basis of the similarity between spinel and rocksalt structures, it is shown that some spinel oxides (e.g., MgCo2O4, etc) can be cathode materials for Mg rechargeable batteries around 150 °C. The Mg insertion into spinel lattices occurs via "intercalation and push-out" process to form a rocksalt phase in the spinel mother phase. For example, by utilizing the valence change from Co(III) to...

Nature of oxygen at rocksalt and spinel oxide surfaces

Nanoscale spinel LiFeTiO4 for intercalation pseudocapacitive Li(+) storage.

Intercalation pseudocapacitive Li(+) storage has been recognized recently in metal oxide materials, wherein Li(+) intercalation into the lattice is not solid-state diffusion-limited. This may bridge the performance gap between electrochemical capacitors and battery materials. To date, only a few materials with desired crystal structure and with well-defined nanoarchitectures have been found to ...

Electronic structure of spinel oxides: zinc aluminate and zinc gallate

The electronic structure of zinc aluminate (ZnAl2O4) and that of zinc gallate (ZnGa2O4) were studied by the self-consistent tight-binding linearized muffin-tin orbital method with the atomic sphere approximation. The calculated results predict these zinc-based spinel oxides to be direct-gap materials. The direct gap at 0 is found to be 4.11 eV for ZnAl2O4 and 2.79 eV for ZnGa2O4. With reference...

Oxygen, magnesium and chromium isotopic ratios of presolar spinel grains

Oxygen isotopic measurements of 20 spinel (MgAl2O4) grains from the CM2 meteorite Murray (average diameter 0.45 m), seven spinel grains from ordinary chondrites (OC, 0.3 to 2 m) and three spinel grains from the CI chondrite Orgueil (0.4 to 0.7 m) have revealed large anomalies and thus established their presolar origin. Their O isotopic ratios fall into all four previously defined groups and ind...